A SYDNEY childcare worker assisted a hysterical mother and her little girl who was "reeking of bleach" after a bottle of toilet cleaner was thrown at them from a car.
Police are questioning two women over a spate of incidents including the "callous" attack on the four-year-old girl in Kellyville Ridge on Wednesday.
The girl was walking with her mother and baby sister, who was being pushed in a pram, when someone hurled a bottle at them from a car on Conrad Road.
Guita Badaoui, who operates Play 'n' Learn Long Daycare, said the mother had just left the centre with girls when the incident occurred.
Moments later, she was back.
"She was beside herself ... she had come running in quite hysterical, she had come to the kitchen not knowing where else to go," Ms Badaoui told Macquarie radio.
"She advised that someone had thrown bleach on her (daughter's) face ... as soon as you walked in and you could smell the bleach that was reeking from this poor child."
The bottle contained toilet cleaner, Ms Badaoui said.
A 20-year-old woman from Glenmore Park and a 22-year-old woman from Ingleburn turned themselves in at Quakers Hill Police Station on Thursday shortly before 1pm (AEST).
Detective Superintendent Gary Mereweather said help from the community prompted the women to come forward.
"The information that we received from community members and people passing through led us onto identifying who owned the vehicle and where it came from and that led to these young girls coming to the police station," he said.
The car was undergoing forensic examination.
The women are also being questioned over other incidents that occurred in the area around the same time.
These include a bottle of energy drink being thrown at a woman walking along Conrad Road and a roll of garbage bags being thrown at a woman on a bicycle.
Ms Badaoui said the girl was at home with her mother and both were doing well.
"It's shocking it has really rocked this community," she said.
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